Synthesis of poly(para-phenylenevinylene) rotaxanes by aqueous Suzuki coupling

Synthesis of poly(para-phenylenevinylene) rotaxanes by aqueous Suzuki coupling

PPV-based polyrotaxanes have been prepared by coupling vinyl boronic acids to aryl iodides in the presence of cyclodextrins, and the crystal structure of a [2]rotaxane of this type has been determined.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2004-01 (1), p.56-57
Hauptverfasser: Terao, Jun, Tang, Andrew, Michels, Jasper J, Krivokapic, Alexander, Anderson, Harry L
Format: Artikel
Sprache:eng
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Zusammenfassung:PPV-based polyrotaxanes have been prepared by coupling vinyl boronic acids to aryl iodides in the presence of cyclodextrins, and the crystal structure of a [2]rotaxane of this type has been determined.
ISSN:1359-7345
DOI:10.1039/b311762f