Towards conformationally-locked difluorosugar analogues: an unexpected sense of dihydroxylation
Difluorinated cyclooctenones, synthesised using RCM, can be used as templates for stereoselective oxidative transformations to products that undergo transannular reactions to afford conformationally-locked analogues of 2-deoxy-2,2-difluorosugars with different stereochemical relationships between th...
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| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2004-02 (3), p.302-303 |
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| container_title | Chemical communications (Cambridge, England) |
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| creator | Fawcett, John Griffiths, Gerry A Percy, Jonathan M Pintat, Stéphane Smith, Clive A Spencer, Neil S Uneyama, Emi |
| description | Difluorinated cyclooctenones, synthesised using RCM, can be used as templates for stereoselective oxidative transformations to products that undergo transannular reactions to afford conformationally-locked analogues of 2-deoxy-2,2-difluorosugars with different stereochemical relationships between the C-2 and C-3 hydroxyl groups. |
| doi_str_mv | 10.1039/b313813e |
| format | Article |
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| fulltext | fulltext |
| identifier | ISSN: 1359-7345 |
| ispartof | Chemical communications (Cambridge, England), 2004-02 (3), p.302-303 |
| issn | 1359-7345 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_80109963 |
| source | MEDLINE; Royal Society of Chemistry Journals Archive (1841-2007); Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Carbohydrate Conformation Cyclization Deoxy Sugars - chemistry Fluorine - chemistry Hydroxylation Stereoisomerism |
| title | Towards conformationally-locked difluorosugar analogues: an unexpected sense of dihydroxylation |
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