Dichloro(dodeca-2,6,10-triene-1,12-diyl)ruthenium(IV): a highly efficient catalyst for the isomerization of allylic alcohols into carbonyl compounds in organic and aqueous media

Dichloro(dodeca-2,6,10-triene-1,12-diyl)ruthenium(IV): a highly efficient catalyst for the isomerization of allylic alcohols into carbonyl compounds in organic and aqueous media

The catalytic activity of the bis(allyl)-ruthenium(iv) complex [Ru([small eta](3):[small eta](2):[small eta](3)-C(12)H(18))Cl(2)] in the transposition of allylic alcohols into carbonyl compounds, both in THF and H(2)O as solvent, is reported.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2004-01 (2), p.232-233
Hauptverfasser: Cadierno, Victorio, García-Garrido, Sergio E, Gimeno, José
Format: Artikel
Sprache:eng
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Zusammenfassung:The catalytic activity of the bis(allyl)-ruthenium(iv) complex [Ru([small eta](3):[small eta](2):[small eta](3)-C(12)H(18))Cl(2)] in the transposition of allylic alcohols into carbonyl compounds, both in THF and H(2)O as solvent, is reported.
ISSN:1359-7345
1364-548X
DOI:10.1039/b313069j