A new route to furanoeremophilane sesquiterpenoids. Synthesis of (+/-)-6[small beta]-hydroxyeuryopsin

The naturally occurring furanoeremophilane 6[small beta]-hydroxyeuryopsin was synthesized by a novel route which involved Stille coupling of a 2-furylstannane with a cyclohexylmethyl bromide, followed by intramolecular formylation of the furan to complete the tricyclic nucleus of the sesquiterpenoid...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2004-01 (1), p.44-45
Hauptverfasser: Shanmugham, M Sundaram, White, James D
Format: Artikel
Sprache:eng
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Zusammenfassung:The naturally occurring furanoeremophilane 6[small beta]-hydroxyeuryopsin was synthesized by a novel route which involved Stille coupling of a 2-furylstannane with a cyclohexylmethyl bromide, followed by intramolecular formylation of the furan to complete the tricyclic nucleus of the sesquiterpenoid.
ISSN:1359-7345