Conversion of d-Glucals into l-Glycals and Mirror-Image Carbohydrates

Conversion of d-Glucals into l-Glycals and Mirror-Image Carbohydrates

l-Glycals can be prepared in seven steps from readily available d-glucals, enabling the facile construction of mirror-image carbohydrates such as the l-lactosamine derivative shown above.

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Bibliographische Detailangaben
Veröffentlicht in:Organic letters 2004-01, Vol.6 (1), p.119-121
Hauptverfasser: Boulineau, Fabien P, Wei, Alexander
Format: Artikel
Sprache:eng
Schlagworte:
Amino Sugars - chemical synthesis
Calcium Gluconate - chemistry
Carbohydrate Conformation
Carbohydrates - chemical synthesis
Carbohydrates - chemistry
Gluconates - chemistry
Models, Chemical
Stereoisomerism
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Zusammenfassung:l-Glycals can be prepared in seven steps from readily available d-glucals, enabling the facile construction of mirror-image carbohydrates such as the l-lactosamine derivative shown above.
ISSN:1523-7060
1523-7052
DOI:10.1021/ol036183m