Selective reduction of a Pd pincer PCP complex to well-defined Pd(0) species

Well-defined dimeric or polymeric Pd(0) complexes [Pd(μ-(iPr)PCHP)](n) (n = 2 or ∞) containing the bridging ligand α,α'-bis(diisopropylphosphino)-m-xylene ((iPr)PCHP) are produced under mild conditions when the cyclometallated PCP pincer complex ((iPr)PCP)Pd-OH reacts with methanol or isopropan...

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Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2010-12, Vol.46 (46), p.8851-8853
Hauptverfasser:	Melero, Cristóbal, Martínez-Prieto, Luis M, Palma, Pilar, del Rio, Diego, Alvarez, Eleuterio, Cámpora, Juan
Format:	Artikel
Sprache:	eng
Schlagworte:	2-Propanol - chemistry Crystallography, X-Ray Ligands Methanol - chemistry Models, Molecular Molecular Structure Organometallic Compounds - chemical synthesis Organometallic Compounds - chemistry Oxidation-Reduction Palladium - chemistry
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Beschreibung
Zusammenfassung:	Well-defined dimeric or polymeric Pd(0) complexes [Pd(μ-(iPr)PCHP)](n) (n = 2 or ∞) containing the bridging ligand α,α'-bis(diisopropylphosphino)-m-xylene ((iPr)PCHP) are produced under mild conditions when the cyclometallated PCP pincer complex ((iPr)PCP)Pd-OH reacts with methanol or isopropanol.
ISSN:	1359-7345 1364-548X
DOI:	10.1039/c0cc02972f