Complete disassembly of carbon disulfide by a ditantalum complex

The side-on end-on dinitrogen complex [PhP(CH(2)SiMe(2)NPh)(2)Ta](μ-H)(2)(μ-η(2):η(1)-N(2)) reacts with CS(2) with complete cleavage of both C=S double bonds and the formation of [PhP(CH(2)SiMe(2)NPh)(2)Ta](μ-S)(2)(μ-CH(2)), which has two bridging sulfides and a bridging methylene unit. Further reac...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2010-12, Vol.46 (46), p.8794-8796
Hauptverfasser: Ballmann, Joachim, Yeo, Alyssa, MacKay, Bruce A, van Rijt, Sabine, Patrick, Brian O, Fryzuk, Michael D
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Sprache:eng
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Zusammenfassung:The side-on end-on dinitrogen complex [PhP(CH(2)SiMe(2)NPh)(2)Ta](μ-H)(2)(μ-η(2):η(1)-N(2)) reacts with CS(2) with complete cleavage of both C=S double bonds and the formation of [PhP(CH(2)SiMe(2)NPh)(2)Ta](μ-S)(2)(μ-CH(2)), which has two bridging sulfides and a bridging methylene unit. Further reaction with H(2) produces CH(4) and the disulfide complex.
ISSN:1359-7345
1364-548X
DOI:10.1039/c0cc03483e