Structure of monoclinic chloro(meso-tetraphenylporphyrinato)iron(III)

Structure of monoclinic chloro(meso-tetraphenylporphyrinato)iron(III)

[FeCl(C44H28N4)], Mr = 704.03, monoclinic, P21/n, a = 10.254 (2), b = 15.969 (3), c = 20.810 (4) A, beta = 90.48 (2) degree, V = 3407.7 A3, Z = 4, Dx = 1.37 g cm-3, Mo K alpha, lambda = 0.71073 A, mu = 5.6 cm-1, F(000) = 363, T = 293 K, R = 0.047 for 3357 unique observed reflections. The iron(III) i...

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Veröffentlicht in:Acta crystallographica. Section C, Crystal structure communications Crystal structure communications, 1989-08, Vol.45 (8), p.1214-1216
Hauptverfasser: Scheidt, W. R., Finnegan, M. G.
Format: Artikel
Sprache:eng
Schlagworte:
Chemical Phenomena
Chemistry, Physical
Condensed matter: structure, mechanical and thermal properties
Crystallization
Crystallography
Exact sciences and technology
Ferric Compounds
Inorganic compounds
Metal complexes
Metalloporphyrins
Molecular Structure
Physics
Structure of solids and liquids
crystallography
Structure of specific crystalline solids
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Zusammenfassung:[FeCl(C44H28N4)], Mr = 704.03, monoclinic, P21/n, a = 10.254 (2), b = 15.969 (3), c = 20.810 (4) A, beta = 90.48 (2) degree, V = 3407.7 A3, Z = 4, Dx = 1.37 g cm-3, Mo K alpha, lambda = 0.71073 A, mu = 5.6 cm-1, F(000) = 363, T = 293 K, R = 0.047 for 3357 unique observed reflections. The iron(III) ion is coordinated to a chloride, Fe--Cl = 2.211 (1) A, and four porphyrinato N atoms, average Fe--N = 2.070 (9) A. The iron(III) is displaced 0.57 A from the mean plane of the 24-atom core.
ISSN:0108-2701
1600-5759
DOI:10.1107/S0108270189000715