Solid-state photo-CIDNP effect observed in phototropin LOV1-C57S by (13)C magic-angle spinning NMR spectroscopy

Solid-state photo-CIDNP effect observed in phototropin LOV1-C57S by (13)C magic-angle spinning NMR spectroscopy

Until now, the solid-state photo-CIDNP effect, discovered in 1994 by Zysmilich and McDermott, has been observed selectively in photosynthetic systems. Here we present the first observation of this effect in a nonphotosynthetic system, the blue-light photoreceptor phototropin LOV1-C57S using (13)C ma...

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Veröffentlicht in:Journal of the American Chemical Society 2010-11, Vol.132 (44), p.15542-15543
Hauptverfasser: Thamarath, Smitha Surendran, Heberle, Joachim, Hore, P J, Kottke, Tilman, Matysik, Jörg
Format: Artikel
Sprache:eng
Schlagworte:
Magnetic Resonance Spectroscopy
Models, Molecular
Phototropins - chemistry
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Zusammenfassung:Until now, the solid-state photo-CIDNP effect, discovered in 1994 by Zysmilich and McDermott, has been observed selectively in photosynthetic systems. Here we present the first observation of this effect in a nonphotosynthetic system, the blue-light photoreceptor phototropin LOV1-C57S using (13)C magic-angle spinning (MAS) NMR.
ISSN:1520-5126
DOI:10.1021/ja1082969