A NEW VERSATILE SYNTHESIS OF CERULENIN

A NEW VERSATILE SYNTHESIS OF CERULENIN

Optically active cerulenin was synthesized by connecting the epoxy aldehyde 4 with the lithiated diene generated from 5. The way of carbon labeling at C-5 was also investigated.

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Bibliographische Detailangaben
Veröffentlicht in:Chemical & pharmaceutical bulletin 1988/03/25, Vol.36(3), pp.1229-1232
Hauptverfasser: Furukawa, Jun, Funabashi, Hiroshi, Morisaki, Naoko, Iwasaki, Shigeo, Okuda, Shigenobu
Format: Artikel
Sprache:eng
Schlagworte:
Antifungal Agents - chemical synthesis
Cerulenin - chemical synthesis
Chemical Phenomena
Chemistry
Exact sciences and technology
fatty acid synthetaase
Heterocyclic compounds
Heterocyclic compounds with o, s, se, te hetero atom and condensed derivatives
Organic chemistry
Preparations and properties
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Beschreibung
Zusammenfassung:Optically active cerulenin was synthesized by connecting the epoxy aldehyde 4 with the lithiated diene generated from 5. The way of carbon labeling at C-5 was also investigated.
ISSN:0009-2363
1347-5223
DOI:10.1248/cpb.36.1229