Synthesis of novel intranuclear diazasteroids

Synthesis of novel intranuclear diazasteroids

By use of the aza Diels-Alder reaction a series of aminoisoquinolines and aminoquinolines have been elaborated to provide an effective synthesis of diverse diazasteroids. In particular, representative 1,11-diaza-, 3,11-diaza-, and 4,11-diazasteroids have been synthesized from cyclopentadiene. From d...

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Veröffentlicht in:Steroids 1995-10, Vol.60 (10), p.693-698
Hauptverfasser: Mellor, John M., Merriman, Glynn D.
Format: Artikel
Sprache:eng
Schlagworte:
Alicyclic compounds, terpenoids, prostaglandins, steroids
aminoisoquinoline
aminoquinoline
Aminoquinolines - chemistry
Azasteroids - chemical synthesis
Chemistry
diazaoxasteroid
diazasteroid
Diels-Alder
Exact sciences and technology
Formaldehyde - chemistry
Magnetic Resonance Spectroscopy
Molecular Structure
Organic chemistry
Preparations and properties
Pyrans - chemistry
Steroids
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Beschreibung
Zusammenfassung:By use of the aza Diels-Alder reaction a series of aminoisoquinolines and aminoquinolines have been elaborated to provide an effective synthesis of diverse diazasteroids. In particular, representative 1,11-diaza-, 3,11-diaza-, and 4,11-diazasteroids have been synthesized from cyclopentadiene. From dihydropyran a 4,11-diaza-15-oxa- d-homosteroid has been obtained.
ISSN:0039-128X
1878-5867
DOI:10.1016/0039-128X(95)00093-6