Total synthesis and absolute configuration determination of (+)-subincanadine F

Total synthesis and absolute configuration determination of (+)-subincanadine F

The first asymmetric synthesis of indole alkaloid (+)-subincanadine F was successfully accomplished with the uncommon 7-endo-trig stereoselective radical cyclization as the key step and its absolute configuration was thus assigned.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2010-11, Vol.46 (44), p.8436-8438
Hauptverfasser: Chen, Pinhong, Cao, Lidong, Tian, Wenhai, Wang, Xinfeng, Li, Chaozhong
Format: Artikel
Sprache:eng
Schlagworte:
Crystallography, X-Ray
Cyclization
Indole Alkaloids - chemical synthesis
Indole Alkaloids - chemistry
Molecular Conformation
Oxidation-Reduction
Stereoisomerism
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Zusammenfassung:The first asymmetric synthesis of indole alkaloid (+)-subincanadine F was successfully accomplished with the uncommon 7-endo-trig stereoselective radical cyclization as the key step and its absolute configuration was thus assigned.
ISSN:1359-7345
1364-548X
DOI:10.1039/c0cc03428b