Chemoselective Catalytic Hydrosilylation of Nitriles

Chemoselective Catalytic Hydrosilylation of Nitriles

Well‐behaved: The ruthenium complex [Cp(iPr3P)Ru(NCCH3)2]+ (Cp=cyclopentadienyl) catalyzes monohydrosilylation of nitriles (see scheme) with unprecedented tolerance of most common functional groups. The catalyst is easily synthesized starting from commercially available compounds, is air‐stable, rec...

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Veröffentlicht in:Angewandte Chemie International Edition 2010-10, Vol.49 (41), p.7553-7556
Hauptverfasser: Gutsulyak, Dmitry V., Nikonov, Georgii I.
Format: Artikel
Sprache:eng
Schlagworte:
chemoselectivity
homogeneous catalysis
hydrosilylation
ruthenium
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Beschreibung
Zusammenfassung:Well‐behaved: The ruthenium complex [Cp(iPr3P)Ru(NCCH3)2]+ (Cp=cyclopentadienyl) catalyzes monohydrosilylation of nitriles (see scheme) with unprecedented tolerance of most common functional groups. The catalyst is easily synthesized starting from commercially available compounds, is air‐stable, recyclable, and works under solvent‐free conditions.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201003069