syn‐Selective Rhodium(I)‐Catalyzed Allylations of Ketimines Proceeding through a Directed CH Activation/Allene Addition Sequence
On a Rh‐oll: Rhodium(I)‐catalyzed CH activations of ketimines and subsequent carborhodation of an allene led to an allyl metal species, which then allylated the imine directing group to give highly functionalized methylene dihydroindenyl amines (see scheme) with excellent regio‐ and diastereoselect...
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| Veröffentlicht in: | Angewandte Chemie (International ed.) 2010-10, Vol.49 (44), p.8181-8184 |
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| container_issue | 44 |
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| container_title | Angewandte Chemie (International ed.) |
| container_volume | 49 |
| creator | Tran, Duc N Cramer, Nicolai |
| description | On a Rh‐oll: Rhodium(I)‐catalyzed CH activations of ketimines and subsequent carborhodation of an allene led to an allyl metal species, which then allylated the imine directing group to give highly functionalized methylene dihydroindenyl amines (see scheme) with excellent regio‐ and diastereoselectivity. |
| doi_str_mv | 10.1002/anie.201004179 |
| format | Article |
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| identifier | ISSN: 1433-7851 |
| ispartof | Angewandte Chemie (International ed.), 2010-10, Vol.49 (44), p.8181-8184 |
| issn | 1433-7851 1521-3773 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_759876534 |
| source | Wiley Online Library Journals Frontfile Complete |
| subjects | allenes allylation annulation CH activation rhodium |
| title | syn‐Selective Rhodium(I)‐Catalyzed Allylations of Ketimines Proceeding through a Directed CH Activation/Allene Addition Sequence |
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