Direct Amination of Secondary Alcohols Using Ammonia

Hydrogen shuttle: For the first time secondary alcohols and ammonia can be directly converted into primary amines with a selectivity of up to 99 % by using a simple ruthenium/phosphine catalyst (see scheme; R1, R2= alkyl, aryl, alkenyl; M=[Ru3(CO)12]; and L=phosphine ligand).

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Bibliographische Detailangaben
Veröffentlicht in:	Angewandte Chemie (International ed.) 2010-10, Vol.49 (44), p.8130-8133
Hauptverfasser:	Pingen, Dennis, Müller, Christian, Vogt, Dieter
Format:	Artikel
Sprache:	eng
Schlagworte:	alcohols Alcohols - chemistry amination Amines - chemistry ammonia Ammonia - chemistry hydrogen ruthenium
Online-Zugang:	Volltext
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Beschreibung
Zusammenfassung:	Hydrogen shuttle: For the first time secondary alcohols and ammonia can be directly converted into primary amines with a selectivity of up to 99 % by using a simple ruthenium/phosphine catalyst (see scheme; R1, R2= alkyl, aryl, alkenyl; M=[Ru3(CO)12]; and L=phosphine ligand).
ISSN:	1433-7851 1521-3773
DOI:	10.1002/anie.201002583