Carborane-Bodipy scaffolds for through space energy transfer

Use of a closo-1,12-dicarbadecaborane backbone to link two different organic dyes separated by ca. 37 Å promotes exclusive through space electronic energy transfer with an efficiency of 81 to 87% with Stoke shifts between 4750 and 2800 cm(-1) depending on the pH.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2010-11, Vol.46 (42), p.7978-7980
Hauptverfasser: Ziessel, Raymond, Ulrich, Gilles, Olivier, Jean Hubert, Bura, Thomas, Sutter, Alexandra
Format: Artikel
Sprache:eng
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Zusammenfassung:Use of a closo-1,12-dicarbadecaborane backbone to link two different organic dyes separated by ca. 37 Å promotes exclusive through space electronic energy transfer with an efficiency of 81 to 87% with Stoke shifts between 4750 and 2800 cm(-1) depending on the pH.
ISSN:1359-7345
1364-548X
DOI:10.1039/c0cc02656e