On the first-neighbor analysis of nucleic acid CD spectra: The definitive T Matrix and considerations of various methods

The first‐neighbor approximation for the representation of double‐stranded polynucleotide CD has been widely applied. Two apparently different formalisms have appeared. We discuss and compare those formalisms and show them to be identical. We present an updated optimum basis set of polydeoxynucleoti...

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Veröffentlicht in:	Biopolymers 1984-11, Vol.23 (11), p.2639-2659
Hauptverfasser:	Allen, Fritz S., Gray, Donald M., Ratliff, Robert L.
Format:	Artikel
Sprache:	eng
Schlagworte:	Base Sequence Biological and medical sciences Circular Dichroism Fundamental and applied biological sciences. Psychology Molecular biophysics Nucleic Acid Conformation Polydeoxyribonucleotides Spectroscopy : techniques and spectras Structure-Activity Relationship
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Beschreibung
Zusammenfassung:	The first‐neighbor approximation for the representation of double‐stranded polynucleotide CD has been widely applied. Two apparently different formalisms have appeared. We discuss and compare those formalisms and show them to be identical. We present an updated optimum basis set of polydeoxynucleotide CD spectra and the resulting first‐neighbor unit contribution matrix derived from these data.
ISSN:	0006-3525 1097-0282
DOI:	10.1002/bip.360231133