Control of Interpenetration for Tuning Structural Flexibility Influences Sorption Properties

Control of Interpenetration for Tuning Structural Flexibility Influences Sorption Properties

Transforming jungle gyms: Structural flexibility and sorption behavior can be tuned by controlling the degree of interpenetration of 3D porous coordination polymers (PCPs). The architectural connectivity of PCPs, even those that are composed of the same chemical components, has a significant impact...

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Veröffentlicht in:Angewandte Chemie (International ed.) 2010-10, Vol.49 (42), p.7660-7664
Hauptverfasser: Bureekaew, Sareeya, Sato, Hiroshi, Matsuda, Ryotaro, Kubota, Yoshiki, Hirose, Raita, Kim, Jungeun, Kato, Kenichi, Takata, Masaki, Kitagawa, Susumu
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carbon dioxide
coordination polymers
host-guest systems
hybrid materials
phase transitions
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container_end_page 7664
container_issue 42
container_start_page 7660
container_title Angewandte Chemie (International ed.)
container_volume 49
creator Bureekaew, Sareeya
Sato, Hiroshi
Matsuda, Ryotaro
Kubota, Yoshiki
Hirose, Raita
Kim, Jungeun
Kato, Kenichi
Takata, Masaki
Kitagawa, Susumu
description Transforming jungle gyms: Structural flexibility and sorption behavior can be tuned by controlling the degree of interpenetration of 3D porous coordination polymers (PCPs). The architectural connectivity of PCPs, even those that are composed of the same chemical components, has a significant impact on the structural flexibility and sorption behavior, which was confirmed by coincident XRPD/adsorption measurements.
doi_str_mv 10.1002/anie.201002259
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source Wiley Online Library Journals Frontfile Complete
subjects carbon dioxide
coordination polymers
host-guest systems
hybrid materials
phase transitions
title Control of Interpenetration for Tuning Structural Flexibility Influences Sorption Properties
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