Control of Interpenetration for Tuning Structural Flexibility Influences Sorption Properties

Control of Interpenetration for Tuning Structural Flexibility Influences Sorption Properties

Transforming jungle gyms: Structural flexibility and sorption behavior can be tuned by controlling the degree of interpenetration of 3D porous coordination polymers (PCPs). The architectural connectivity of PCPs, even those that are composed of the same chemical components, has a significant impact...

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Veröffentlicht in:Angewandte Chemie (International ed.) 2010-10, Vol.49 (42), p.7660-7664
Hauptverfasser: Bureekaew, Sareeya, Sato, Hiroshi, Matsuda, Ryotaro, Kubota, Yoshiki, Hirose, Raita, Kim, Jungeun, Kato, Kenichi, Takata, Masaki, Kitagawa, Susumu
Format: Artikel
Sprache:eng
Schlagworte:
carbon dioxide
coordination polymers
host-guest systems
hybrid materials
phase transitions
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Zusammenfassung:Transforming jungle gyms: Structural flexibility and sorption behavior can be tuned by controlling the degree of interpenetration of 3D porous coordination polymers (PCPs). The architectural connectivity of PCPs, even those that are composed of the same chemical components, has a significant impact on the structural flexibility and sorption behavior, which was confirmed by coincident XRPD/adsorption measurements.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201002259