Rearrangement products of 3-methanesulfonyl-N-methyl-N-nitroaniline

Rearrangement products of 3-methanesulfonyl-N-methyl-N-nitroaniline

Two isomeric products (C(8)H(10)N(2)O(4)S) of the rearrangement of 3-methanesulfonyl-N-methyl-N-nitroaniline have been investigated, viz. 3-methanesulfonyl-N-methyl-2-nitroaniline, which was the main product of the rearrangement, and 5-methanesulfonyl-N-methyl-2-nitroaniline. In both molecules, the...

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Veröffentlicht in:Acta crystallographica. Section C, Crystal structure communications Crystal structure communications, 2003-10, Vol.59 (Pt 10), p.o564-o566
Hauptverfasser: ZARYCHTA, Bartosz, DASZKIEWICZ, Zdzisław, KYZIOŁ, Janusz B, ZALESKI, Jacek
Format: Artikel
Sprache:eng
Schlagworte:
Aliphatic, non-condensed and condensed benzenic, and alicyclic compounds
Condensed matter: structure, mechanical and thermal properties
Exact sciences and technology
Organic compounds
Physics
Structure of solids and liquids
crystallography
Structure of specific crystalline solids
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Zusammenfassung:Two isomeric products (C(8)H(10)N(2)O(4)S) of the rearrangement of 3-methanesulfonyl-N-methyl-N-nitroaniline have been investigated, viz. 3-methanesulfonyl-N-methyl-2-nitroaniline, which was the main product of the rearrangement, and 5-methanesulfonyl-N-methyl-2-nitroaniline. In both molecules, the aromatic rings are appreciably deformed towards ortho-quinonoidal geometry by electronic and steric interactions. The crystal structure is stabilized, in both cases, by weak C-H.O hydrogen bonds.
ISSN:0108-2701
1600-5759
DOI:10.1107/S0108270103017888