Chelation-Controlled Bergman Cyclization: Synthesis and Reactivity of Enediynyl Ligands

This article describes cases where the rate of Bergman cyclization is perturbed by the presence of metal ions or organometallic reagents.

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Bibliographische Detailangaben
Veröffentlicht in:	Chemical reviews 2003-10, Vol.103 (10), p.4077-4094
Hauptverfasser:	Basak, Amit, Mandal, Subrata, Bag, Subhendu Sekhar
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkenes - chemistry Alkynes - chemistry Benzene Derivatives - chemical synthesis Benzene Derivatives - chemistry Chelating Agents - chemistry Chemistry Chemistry, Organic - methods Cyclization Heterocyclic Compounds - chemical synthesis Heterocyclic Compounds - chemistry Ions Ligands Metals Molecular Conformation Molecular Structure Organometallic Compounds - chemical synthesis Organometallic Compounds - chemistry Oxidation-Reduction
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Beschreibung
Zusammenfassung:	This article describes cases where the rate of Bergman cyclization is perturbed by the presence of metal ions or organometallic reagents.
ISSN:	0009-2665 1520-6890
DOI:	10.1021/cr020069k