Synthesis, molecular structure and chemical properties of a new tungstosilicate with an open Wells-Dawson structure, alpha-[Si2W18O66]16
Acidification of K10A-alpha-[SiW9O34] in aqueous solution leads to the formation of alpha-[Si2W18O66]16-, built up from two A-alpha-[SiW9O34] subunits, which reacts with metal cations to form potassium and mixed potassium-transition metal complexes.
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| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2003-09 (18), p.2360-2361 |
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| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | Acidification of K10A-alpha-[SiW9O34] in aqueous solution leads to the formation of alpha-[Si2W18O66]16-, built up from two A-alpha-[SiW9O34] subunits, which reacts with metal cations to form potassium and mixed potassium-transition metal complexes. |
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| ISSN: | 1359-7345 1364-548X |
| DOI: | 10.1039/b307276b |