Group 3-centred dehydrocoupling of Me2NH·BH3

Stoichiometric and catalytic reactions of group 3 (Sc, Y) amides with Me(2)NH·BH(3) result in formation of the corresponding amidoborane derivatives and dehydrogenative coupling of two amine borane fragments under mild conditions.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2010-10, Vol.46 (40), p.7587-7589
Hauptverfasser: Hill, Michael S, Kociok-Köhn, Gabriele, Robinson, Thomas P
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container_title Chemical communications (Cambridge, England)
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creator Hill, Michael S
Kociok-Köhn, Gabriele
Robinson, Thomas P
description Stoichiometric and catalytic reactions of group 3 (Sc, Y) amides with Me(2)NH·BH(3) result in formation of the corresponding amidoborane derivatives and dehydrogenative coupling of two amine borane fragments under mild conditions.
doi_str_mv 10.1039/c0cc02810j
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source Royal Society Of Chemistry Journals; Alma/SFX Local Collection
title Group 3-centred dehydrocoupling of Me2NH·BH3
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