Group 3-centred dehydrocoupling of Me2NH·BH3

Group 3-centred dehydrocoupling of Me2NH·BH3

Stoichiometric and catalytic reactions of group 3 (Sc, Y) amides with Me(2)NH·BH(3) result in formation of the corresponding amidoborane derivatives and dehydrogenative coupling of two amine borane fragments under mild conditions.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2010-10, Vol.46 (40), p.7587-7589
Hauptverfasser: Hill, Michael S, Kociok-Köhn, Gabriele, Robinson, Thomas P
Format: Artikel
Sprache:eng
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Zusammenfassung:Stoichiometric and catalytic reactions of group 3 (Sc, Y) amides with Me(2)NH·BH(3) result in formation of the corresponding amidoborane derivatives and dehydrogenative coupling of two amine borane fragments under mild conditions.
ISSN:1359-7345
1364-548X
DOI:10.1039/c0cc02810j