Anion complexation and sensing using modified urea and thiourea-based receptors

This critical review highlights recent advances in the structurally modified (thio)urea-based receptors for anion complexation and sensing. Modifications of the (thio)urea structure are aimed at a better anion binding in terms of higher binding constant, anion selectivity and feasibility. Major (thi...

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Veröffentlicht in:Chemical Society reviews 2010-01, Vol.39 (10), p.3729-3745
Hauptverfasser: Li, Ai-Fang, Wang, Jin-He, Wang, Fang, Jiang, Yun-Bao
Format: Artikel
Sprache:eng
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Zusammenfassung:This critical review highlights recent advances in the structurally modified (thio)urea-based receptors for anion complexation and sensing. Modifications of the (thio)urea structure are aimed at a better anion binding in terms of higher binding constant, anion selectivity and feasibility. Major (thio)urea receptors are reviewed as N-alkyl, N-aryl and N-amido/N-amino (thio)ureas. Hints for designing (thio)urea-based receptors for anions are discussed (102 references).
ISSN:0306-0012
1460-4744
DOI:10.1039/b926160p