A Metal−Organic Framework with a Covalently Prefabricated Porous Organic Linker

A Metal−Organic Framework with a Covalently Prefabricated Porous Organic Linker

We report here the synthesis of a metal−organic framework comprising an organic cage linker with covalently prefabricated, intrinsic porosity. The network can be compared to a porous rock salt structure where the pores are partially filled by charge-balancing cations.

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Journal of the American Chemical Society 2010-09, Vol.132 (37), p.12773-12775
Hauptverfasser: Swamy, Shashikala I, Bacsa, John, Jones, James T. A, Stylianou, Kyriakos C, Steiner, Alexander, Ritchie, Lyndsey K, Hasell, Tom, Gould, Jamie A, Laybourn, Andrea, Khimyak, Yaroslav Z, Adams, Dave J, Rosseinsky, Matthew J, Cooper, Andrew I
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:We report here the synthesis of a metal−organic framework comprising an organic cage linker with covalently prefabricated, intrinsic porosity. The network can be compared to a porous rock salt structure where the pores are partially filled by charge-balancing cations.
ISSN:0002-7863
1520-5126
DOI:10.1021/ja104083y