Sub-ppm Detection of Nerve Agents Using Chemically Functionalized Silicon Nanoribbon Field-Effect Transistors

A chemical receptor specific to traces of organophosphorus agents (OPs) has been synthesized and grafted to a silicon nanoribbon field‐effect transistor (SiNR‐FET). X‐ray structures illustrate the structural modifications of the receptor upon exposure to nerve agent simulants. A highly sensitive and...

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Veröffentlicht in:Angewandte Chemie (International ed.) 2010-06, Vol.49 (24), p.4063-4066
Hauptverfasser: Clavaguera, Simon, Carella, Alexandre, Caillier, Laurent, Celle, Caroline, Pécaut, Jacques, Lenfant, Stéphane, Vuillaume, Dominique, Simonato, Jean-Pierre
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container_end_page 4066
container_issue 24
container_start_page 4063
container_title Angewandte Chemie (International ed.)
container_volume 49
creator Clavaguera, Simon
Carella, Alexandre
Caillier, Laurent
Celle, Caroline
Pécaut, Jacques
Lenfant, Stéphane
Vuillaume, Dominique
Simonato, Jean-Pierre
description A chemical receptor specific to traces of organophosphorus agents (OPs) has been synthesized and grafted to a silicon nanoribbon field‐effect transistor (SiNR‐FET). X‐ray structures illustrate the structural modifications of the receptor upon exposure to nerve agent simulants. A highly sensitive and selective detector of OPs can be obtained by monitoring the Drain‐Source current of the SiNR‐FET at an optimum back‐gate voltage as a function of time.
doi_str_mv 10.1002/anie.201000122
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source MEDLINE; Wiley Online Library Journals Frontfile Complete
subjects Chemical Warfare Agents - analysis
Chemical Warfare Agents - chemistry
Crystallography, X-Ray
field-effect transistors
Gases - chemistry
Microscopy, Atomic Force
Molecular Conformation
nanotechnology
Nanotubes - chemistry
nerve agents
Organophosphorus Compounds - analysis
Organophosphorus Compounds - chemistry
sensors
Silicon - chemistry
silicon nanoribbons
Transistors, Electronic
title Sub-ppm Detection of Nerve Agents Using Chemically Functionalized Silicon Nanoribbon Field-Effect Transistors
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