Sub-ppm Detection of Nerve Agents Using Chemically Functionalized Silicon Nanoribbon Field-Effect Transistors

A chemical receptor specific to traces of organophosphorus agents (OPs) has been synthesized and grafted to a silicon nanoribbon field‐effect transistor (SiNR‐FET). X‐ray structures illustrate the structural modifications of the receptor upon exposure to nerve agent simulants. A highly sensitive and...

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Veröffentlicht in:Angewandte Chemie (International ed.) 2010-06, Vol.49 (24), p.4063-4066
Hauptverfasser: Clavaguera, Simon, Carella, Alexandre, Caillier, Laurent, Celle, Caroline, Pécaut, Jacques, Lenfant, Stéphane, Vuillaume, Dominique, Simonato, Jean-Pierre
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Sprache:eng
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Zusammenfassung:A chemical receptor specific to traces of organophosphorus agents (OPs) has been synthesized and grafted to a silicon nanoribbon field‐effect transistor (SiNR‐FET). X‐ray structures illustrate the structural modifications of the receptor upon exposure to nerve agent simulants. A highly sensitive and selective detector of OPs can be obtained by monitoring the Drain‐Source current of the SiNR‐FET at an optimum back‐gate voltage as a function of time.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201000122