Copper-Catalyzed Olefin Aminoacetoxylation

Copper-Catalyzed Olefin Aminoacetoxylation

A new catalyst system for intramolecular olefin aminoacetoxylation is described. In contrast to previously reported palladium- and copper-catalyzed systems, the conditions outlined in this communication favor piperdine formation with terminal olefin substrates and induce cyclization with traditional...

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Veröffentlicht in:Organic letters 2010-09, Vol.12 (18), p.4110-4113
Hauptverfasser: Mancheno, Danny E, Thornton, Aaron R, Stoll, Armin H, Kong, Aidi, Blakey, Simon B
Format: Artikel
Sprache:eng
Schlagworte:
Acetone - chemistry
Alkenes - chemistry
Amines - chemistry
Catalysis
Copper - chemistry
Cyclization
Molecular Structure
Oxidation-Reduction
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Zusammenfassung:A new catalyst system for intramolecular olefin aminoacetoxylation is described. In contrast to previously reported palladium- and copper-catalyzed systems, the conditions outlined in this communication favor piperdine formation with terminal olefin substrates and induce cyclization with traditionally less reactive disubstituted olefins.
ISSN:1523-7060
1523-7052
DOI:10.1021/ol101702w