Self-assembled organic-inorganic hybrid silica with ionic liquid framework: a novel support for the catalytic enantioselective Strecker reaction of imines using Yb(OTf)(3)-pybox catalyst

Yb(OTf)(3)-pybox is immobilized in a novel self-assembled ionic liquid hybrid silica and has been successfully applied as a catalyst for the asymmetric Strecker hydrocyanation of aldimines. This catalytic system can be reused for at least 6 times without any significant loss of activity and enantios...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2010-10, Vol.46 (37), p.6947-6949
Hauptverfasser: Karimi, Babak, Maleki, Aziz, Elhamifar, Dawood, Clark, James H, Hunt, Andrew J
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Sprache:eng
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Zusammenfassung:Yb(OTf)(3)-pybox is immobilized in a novel self-assembled ionic liquid hybrid silica and has been successfully applied as a catalyst for the asymmetric Strecker hydrocyanation of aldimines. This catalytic system can be reused for at least 6 times without any significant loss of activity and enantioselectivity.
ISSN:1364-548X
DOI:10.1039/c0cc01426e