N-Heterocyclic Carbene Embedded in an N-Confused Porphyrin Framework

N-Heterocyclic Carbene Embedded in an N-Confused Porphyrin Framework

A rhenium(I) complex of an N-heterocyclic carbene ligand embedded in an N-confused porphyrin core was serendipitously synthesized by the reaction of an inner-methylated N-confused porphyrin with Re2(CO)10.

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Veröffentlicht in:Inorganic chemistry 2010-09, Vol.49 (18), p.8182-8184
Hauptverfasser: Toganoh, Motoki, Hihara, Takayoshi, Furuta, Hiroyuki
Format: Artikel
Sprache:eng
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Zusammenfassung:A rhenium(I) complex of an N-heterocyclic carbene ligand embedded in an N-confused porphyrin core was serendipitously synthesized by the reaction of an inner-methylated N-confused porphyrin with Re2(CO)10.
ISSN:0020-1669
1520-510X
DOI:10.1021/ic1016356