Selective P----P and P----O----P Bond Formations through Copper-Catalyzed Aerobic Oxidative Dehydrogenative Couplings of H-Phosphonates

Selective P----P and P----O----P Bond Formations through Copper-Catalyzed Aerobic Oxidative Dehydrogenative Couplings of H-Phosphonates

Different copper complexes selectively catalyze the aerobic oxidative coupling of H‐phosphonates to afford either hypophosphates and pyrophosphates in high yields with high selectivity (see scheme; tmeda=N,N,N′,N′‐tetramethylethylenediamine).

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Veröffentlicht in:Angewandte Chemie (International ed.) 2010-09, Vol.49 (38), p.6852-6855
Hauptverfasser: Zhou, Yongbo, Yin, Shuangfeng, Gao, Yuxing, Zhao, Yufen, Goto, Midori, Han, Li-Biao
Format: Artikel
Sprache:eng
Schlagworte:
copper
dehydrogenation
homogeneous catalysis
phosphorus
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Zusammenfassung:Different copper complexes selectively catalyze the aerobic oxidative coupling of H‐phosphonates to afford either hypophosphates and pyrophosphates in high yields with high selectivity (see scheme; tmeda=N,N,N′,N′‐tetramethylethylenediamine).
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201003484