Influences of template concentration and epoxy functionality on porous epoxy systems: Characteristics of thermal stability, optical, dielectric, and mechanical properties

Two different multi-porous epoxy thermosets (MPETs), bi-functionality of DGEBA and tri-functionality of TGTPM, were prepared foremost for the interaction of template concentration and epoxy functionality under several physical properties. By performing an automated mercury porosimeter test, we found...

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Veröffentlicht in:Polymer degradation and stability 2010-04, Vol.95 (4), p.600-609
Hauptverfasser: Dai, Chung-Feng, Weng, Chang-Jian, Li, Pei-Ru, Yeh, Jui-Ming
Format: Artikel
Sprache:eng
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Zusammenfassung:Two different multi-porous epoxy thermosets (MPETs), bi-functionality of DGEBA and tri-functionality of TGTPM, were prepared foremost for the interaction of template concentration and epoxy functionality under several physical properties. By performing an automated mercury porosimeter test, we found out template concentration was critical to the amount of voids/pores. Meanwhile, epoxy functionality decided the formation of porous structure through SEM. Comparing with TGTPM MPETs system, the DGEBA MPETs system with 20 wt% template displayed appreciable T g and tan δ properties while the phenomenon exhibited higher thermal stability property. Additionally, thermal conductivity patterns show the DGEBA MPETs system is a remarkable material of thermal resistance. However, it reduces optical clarity, dielectric permittivity and mechanical strength according to the UV–visible spectroscopy, LCR meter, and DMA, normally. Therefore, we can understand that template concentration and epoxy functionality are key factors of physical degradation and stability in porous epoxy materials.
ISSN:0141-3910
1873-2321
DOI:10.1016/j.polymdegradstab.2009.12.008