Structure and properties of polypropylene/hydrotalcite nanocomposites
This article presents the study of the modification of the particle/matrix interface region and its effects on the structure and dynamic mechanical behavior of polypropylene (PP)/hydrotalcite nanocomposites prepared by melt extrusion. The interface modification was promoted by combinying the organop...
Gespeichert in:
Veröffentlicht in: | Polymer composites 2010-05, Vol.31 (5), p.870-878 |
---|---|
Hauptverfasser: | , , , , |
Format: | Artikel |
Sprache: | eng |
Schlagworte: | |
Online-Zugang: | Volltext |
Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
Zusammenfassung: | This article presents the study of the modification of the particle/matrix interface region and its effects on the structure and dynamic mechanical behavior of polypropylene (PP)/hydrotalcite nanocomposites prepared by melt extrusion. The interface modification was promoted by combinying the organophillization of the hydrotalcite particles with blending the PP with a maleic anhydride‐grafted‐PP (PP‐g‐MAH) or a maleic anhydride‐grafted‐poly(styrene‐co‐ethylenebutylene‐co‐styrene) (SEBS‐g‐MAH). Sodium dodecyl sulphate was used to promote the organophillization of the hydrotalcite particles. X‐ray diffraction (XRD) and transmission electron microscopy (TEM) showed a partially exfoliated hydrotalcite structure, with an increasing exfoliation being achieved by adding a compatibilizer and organo‐modifying the particles. Values of the Young's modulus (E), storage modulus (E′), maximum tensile strength (σmax), neck propagation strength (σneck), and elongation at break (εb) were found to depend both on the nature of the particle matrix interface as well as on the type of compatibilizer. Also, nanocomposites prepared with the organophillized particles showed lower Tg and loss factor values. POLYM. COMPOS., 2010. © 2009 Society of Plastics Engineers |
---|---|
ISSN: | 0272-8397 1548-0569 |
DOI: | 10.1002/pc.20869 |