Novel catalyst-support interaction for direct formic acid fuel cell anodes: Pd electrodeposition on surface-modified graphite felt

The electrodeposition of Pd on graphite felt (GF, thickness ~3 mm in uncompressed state) was studied and the resulting catalyst was compared with Pt-Ru/GF for the electro-oxidation of formic acid. A micellar solution composed of the non-ionic surfactant Triton X-102 and an aqueous phase containing PdCl 2 were utilized for the galvanostatic electrodeposition of Pd nanoparticles. The presence of the surfactant during electrodeposition coupled with pretreatment of the GF surface by a Shipley-type method (PdCl 2 + SnCl 2 solution) creating nucleation sites had a major impact on the Pd catalyst morphology and penetration throughout the electrode thickness, affecting, therefore, the electrocatalytic activity toward formic acid oxidation. It was found that large (~1,000 nm) Pd particles with smooth surface favored the indirect CO ad pathway, while Pd nanoparticles (diameter