Ultra-Broad Optical Amplification and Two-Colour Amplified Spontaneous Emission in Binary Blends of Insulated Molecular Wires

We demonstrate optical amplification over a band >850 meV, via simultaneous exploitation of stimulated emission from mixed polymer systems in which energy transfer from the higher to lower‐gap material is inhibited thanks to a complex interplay between morphology and interchain decoupling, driven by chain encapsulation. Amplified spontaneous emission (ASE) is obtained both with ad‐hoc pumping into the relevant bands or with a single excitation (400nm) able to sustain ASE at both wavelengths simultaneously (two‐colour ASE).