Diverse reactions of sterically-protected 1,3-diphosphacyclobutane-2,4-diyls with hydride

Hydride-induced elimination of resonance stabilized substituents from a phosphorus center of 1,3-diphosphacyclobutane-2,4-diyls leads to the formation of versatile cyclic phosphaallyl anions that are useful for the construction of various electrophile-modified biradical species.

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Veröffentlicht in:Dalton transactions : an international journal of inorganic chemistry 2010-09, Vol.39 (35), p.8281-8287
Hauptverfasser: Ito, Shigekazu, Miura, Joji, Morita, Noboru, Yoshifuji, Masaaki, Arduengo, 3rd, Anthony J
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container_issue 35
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container_title Dalton transactions : an international journal of inorganic chemistry
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creator Ito, Shigekazu
Miura, Joji
Morita, Noboru
Yoshifuji, Masaaki
Arduengo, 3rd, Anthony J
description Hydride-induced elimination of resonance stabilized substituents from a phosphorus center of 1,3-diphosphacyclobutane-2,4-diyls leads to the formation of versatile cyclic phosphaallyl anions that are useful for the construction of various electrophile-modified biradical species.
doi_str_mv 10.1039/c0dt00532k
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title Diverse reactions of sterically-protected 1,3-diphosphacyclobutane-2,4-diyls with hydride
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