Diverse reactions of sterically-protected 1,3-diphosphacyclobutane-2,4-diyls with hydride
Hydride-induced elimination of resonance stabilized substituents from a phosphorus center of 1,3-diphosphacyclobutane-2,4-diyls leads to the formation of versatile cyclic phosphaallyl anions that are useful for the construction of various electrophile-modified biradical species.
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| Veröffentlicht in: | Dalton transactions : an international journal of inorganic chemistry 2010-09, Vol.39 (35), p.8281-8287 |
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| Hauptverfasser: | , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | Hydride-induced elimination of resonance stabilized substituents from a phosphorus center of 1,3-diphosphacyclobutane-2,4-diyls leads to the formation of versatile cyclic phosphaallyl anions that are useful for the construction of various electrophile-modified biradical species. |
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| ISSN: | 1477-9226 1477-9234 |
| DOI: | 10.1039/c0dt00532k |