A Zinc(II)-Included Hemicryptophane: Facile Synthesis, Characterization, and Catalytic Activity
A zinc(II)-included hemicryptophane, which has a zinc(II) center embedded in the cavity, was synthesized and characterized. The catalytic activity of the hemicryptophane was tested in the hydrolysis of methyl para-nitrophenyl carbonate (MPC). A direct comparison between the hemicryptophane and the m...
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| Veröffentlicht in: | Inorganic chemistry 2010-08, Vol.49 (16), p.7220-7222 |
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| container_end_page | 7222 |
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| container_issue | 16 |
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| container_title | Inorganic chemistry |
| container_volume | 49 |
| creator | Makita, Yoshimasa Sugimoto, Kazuya Furuyoshi, Kenta Ikeda, Keisuke Fujiwara, Shin-ichi Shin-ike, Tsutomu Ogawa, Akiya |
| description | A zinc(II)-included hemicryptophane, which has a zinc(II) center embedded in the cavity, was synthesized and characterized. The catalytic activity of the hemicryptophane was tested in the hydrolysis of methyl para-nitrophenyl carbonate (MPC). A direct comparison between the hemicryptophane and the model complex, which lacks a cavity, demonstrated that the cage structure enhanced the catalytic activity. |
| doi_str_mv | 10.1021/ic100725j |
| format | Article |
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The catalytic activity of the hemicryptophane was tested in the hydrolysis of methyl para-nitrophenyl carbonate (MPC). A direct comparison between the hemicryptophane and the model complex, which lacks a cavity, demonstrated that the cage structure enhanced the catalytic activity.</description><identifier>ISSN: 0020-1669</identifier><identifier>EISSN: 1520-510X</identifier><identifier>DOI: 10.1021/ic100725j</identifier><identifier>PMID: 20690728</identifier><language>eng</language><publisher>United States: American Chemical Society</publisher><subject>Catalysis ; Models, Molecular ; Molecular Conformation ; Organometallic Compounds - chemical synthesis ; Organometallic Compounds - chemistry ; Polycyclic Compounds ; Triazoles - chemistry ; Zinc - chemistry</subject><ispartof>Inorganic chemistry, 2010-08, Vol.49 (16), p.7220-7222</ispartof><rights>Copyright © 2010 American Chemical Society</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a380t-ff59a783100e99a3be7b906d8d413c167733bb75dc09328059aa7727505d00303</citedby><cites>FETCH-LOGICAL-a380t-ff59a783100e99a3be7b906d8d413c167733bb75dc09328059aa7727505d00303</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/ic100725j$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/ic100725j$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,776,780,2752,27053,27901,27902,56713,56763</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/20690728$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Makita, Yoshimasa</creatorcontrib><creatorcontrib>Sugimoto, Kazuya</creatorcontrib><creatorcontrib>Furuyoshi, Kenta</creatorcontrib><creatorcontrib>Ikeda, Keisuke</creatorcontrib><creatorcontrib>Fujiwara, Shin-ichi</creatorcontrib><creatorcontrib>Shin-ike, Tsutomu</creatorcontrib><creatorcontrib>Ogawa, Akiya</creatorcontrib><title>A Zinc(II)-Included Hemicryptophane: Facile Synthesis, Characterization, and Catalytic Activity</title><title>Inorganic chemistry</title><addtitle>Inorg. 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| ispartof | Inorganic chemistry, 2010-08, Vol.49 (16), p.7220-7222 |
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| language | eng |
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| source | ACS Publications; MEDLINE |
| subjects | Catalysis Models, Molecular Molecular Conformation Organometallic Compounds - chemical synthesis Organometallic Compounds - chemistry Polycyclic Compounds Triazoles - chemistry Zinc - chemistry |
| title | A Zinc(II)-Included Hemicryptophane: Facile Synthesis, Characterization, and Catalytic Activity |
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