A Zinc(II)-Included Hemicryptophane: Facile Synthesis, Characterization, and Catalytic Activity

A Zinc(II)-Included Hemicryptophane: Facile Synthesis, Characterization, and Catalytic Activity

A zinc(II)-included hemicryptophane, which has a zinc(II) center embedded in the cavity, was synthesized and characterized. The catalytic activity of the hemicryptophane was tested in the hydrolysis of methyl para-nitrophenyl carbonate (MPC). A direct comparison between the hemicryptophane and the m...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Inorganic chemistry 2010-08, Vol.49 (16), p.7220-7222
Hauptverfasser: Makita, Yoshimasa, Sugimoto, Kazuya, Furuyoshi, Kenta, Ikeda, Keisuke, Fujiwara, Shin-ichi, Shin-ike, Tsutomu, Ogawa, Akiya
Format: Artikel
Sprache:eng
Schlagworte:
Catalysis
Models, Molecular
Molecular Conformation
Organometallic Compounds - chemical synthesis
Organometallic Compounds - chemistry
Polycyclic Compounds
Triazoles - chemistry
Zinc - chemistry
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:A zinc(II)-included hemicryptophane, which has a zinc(II) center embedded in the cavity, was synthesized and characterized. The catalytic activity of the hemicryptophane was tested in the hydrolysis of methyl para-nitrophenyl carbonate (MPC). A direct comparison between the hemicryptophane and the model complex, which lacks a cavity, demonstrated that the cage structure enhanced the catalytic activity.
ISSN:0020-1669
1520-510X
DOI:10.1021/ic100725j