A coumarin based ICT probe for fluoride in aqueous medium with its real application
A new coumarin based hydrazone (receptor 1) synthesized by modifying one of our earlier reported receptor detected fluoride ion selectively through naked eye in aq. DMSO (5:95, v/v). It was also able to detect fluoride through naked eye in a toothpaste sample. The addition of 1 equiv. of fluoride as...
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Veröffentlicht in: | Talanta (Oxford) 2010-06, Vol.82 (1), p.312-318 |
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Sprache: | eng |
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Zusammenfassung: | A new coumarin based hydrazone (receptor 1) synthesized by modifying one of our earlier reported receptor detected fluoride ion selectively through naked eye in aq. DMSO (5:95, v/v). It was also able to detect fluoride through naked eye in a toothpaste sample. The addition of 1
equiv. of fluoride as its tetrabutylammonium salt to the 5
×
10
−5
M aq. DMSO solution of the receptor 1 produced red color while the similar addition of acetate produced faint pink color. The dihydrogenphosphate and a variety of other anions were not able to produce any significant color change with receptor 1 under similar experimental conditions. The corresponding UV–vis measurements showed a bathochromic shifting of 455
nm band of receptor 1 to 514 and 484
nm for fluoride and acetate, respectively. The non-linear fittings of corresponding UV–vis titration data in 1:1 binding equation yielded association constants in 10
5:1 ratio for fluoride and acetate, respectively. The
1H NMR titrations studies shade further light on their mode of binding with receptor 1. The quantum mechanical calculations through time dependant density functional theory (TD-DFT) using basis set b3lyp/6-311g** supported our experimental findings nicely. |
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ISSN: | 0039-9140 1873-3573 |
DOI: | 10.1016/j.talanta.2010.04.041 |