Synthesis and Characterization of Teranthene: A Singlet Biradical Polycyclic Aromatic Hydrocarbon Having Kekulé Structures

Synthesis and Characterization of Teranthene: A Singlet Biradical Polycyclic Aromatic Hydrocarbon Having Kekulé Structures

A teranthene derivative has been successfully isolated in a crystalline form for the first time. Geometrical considerations and physical property investigations indicate that the molecule possesses prominent biradical character in the ground state.

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Veröffentlicht in:Journal of the American Chemical Society 2010-08, Vol.132 (32), p.11021-11023
Hauptverfasser: Konishi, Akihito, Hirao, Yasukazu, Nakano, Masayoshi, Shimizu, Akihiro, Botek, Edith, Champagne, Benoît, Shiomi, Daisuke, Sato, Kazunobu, Takui, Takeji, Matsumoto, Kouzou, Kurata, Hiroyuki, Kubo, Takashi
Format: Artikel
Sprache:eng
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Zusammenfassung:A teranthene derivative has been successfully isolated in a crystalline form for the first time. Geometrical considerations and physical property investigations indicate that the molecule possesses prominent biradical character in the ground state.
ISSN:0002-7863
1520-5126
DOI:10.1021/ja1049737