Adsorption and Reactivity of 2,3-Dihydrofuran and 2,5-Dihydrofuran on Pd(111): Influence of the CC Position on the Reactivity of Cyclic Ethers

Adsorption and Reactivity of 2,3-Dihydrofuran and 2,5-Dihydrofuran on Pd(111): Influence of the CC Position on the Reactivity of Cyclic Ethers

High-resolution electron energy loss spectroscopy (HREELS) and temperature-programmed desorption (TPD) were used to study the adsorption and thermal chemistry of 2,3-dihydrofuran (2,3-DHF) and 2,5-dihydrofuran (2,5-DHF) on Pd(111). The results, paired with earlier computational results, indicate tha...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Langmuir 2010-08, Vol.26 (16), p.13320-13332
Hauptverfasser: Horiuchi, Clay M, Medlin, J. Will
Format: Artikel
Sprache:eng
Schlagworte:
Furans - chemistry
Interfaces: Adsorption, Reactions, Films, Forces
Models, Chemical
Palladium - chemistry
Spectroscopy, Electron Energy-Loss
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:High-resolution electron energy loss spectroscopy (HREELS) and temperature-programmed desorption (TPD) were used to study the adsorption and thermal chemistry of 2,3-dihydrofuran (2,3-DHF) and 2,5-dihydrofuran (2,5-DHF) on Pd(111). The results, paired with earlier computational results, indicate that 2,3-DHF and 2,5-DHF both adsorb on Pd(111) primarily via their respective olefin functional groups at low temperature (
ISSN:0743-7463
1520-5827
DOI:10.1021/la1019394