Enhanced electrogenerated chemiluminescence of a ruthenium tris(2,2')bipyridyl/tripropylamine system on a boron-doped diamond nanograss array

Enhanced electrogenerated chemiluminescence of a ruthenium tris(2,2')bipyridyl/tripropylamine system on a boron-doped diamond nanograss array

Significant enhancement of the ECL signals from the Ru(bpy)(3)(2+)/TPA system was achieved when using a BDD nanograss array, mainly because of the highly facile oxidation of TPA. The facile oxidation of TPA is due to the superior properties of the BDD nanograss array, such as improved electrocatalyt...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2010-08, Vol.46 (31), p.5793-5795
Hauptverfasser: Yang, Yongtak, Oh, Jeong-Wook, Kim, Yang-Rae, Terashima, Chiaki, Fujishima, Akira, Kim, Jong Seung, Kim, Hasuck
Format: Artikel
Sprache:eng
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Zusammenfassung:Significant enhancement of the ECL signals from the Ru(bpy)(3)(2+)/TPA system was achieved when using a BDD nanograss array, mainly because of the highly facile oxidation of TPA. The facile oxidation of TPA is due to the superior properties of the BDD nanograss array, such as improved electrocatalytic activity and accelerated electron transfer.
ISSN:1359-7345
1364-548X
DOI:10.1039/c0cc00773k