The influence of temperature on the oxidation of ferrous hydroxide in sulphated aqueous medium: Activation energies of formation of the products and hyperfine structure of magnetite

Oxidation processes of the initial products at any value of the ratio R = {[FeSO 4]/[OH −]} initial is characterized by a reduction in the overall oxidation time as the temperature of the medium increases; this has been valuable in the determination of the various activation energies. Magnetite pred...

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Veröffentlicht in:Corrosion science 1991, Vol.32 (9), p.985-1001
Hauptverfasser: Olowe, A.A, Pauron, B, Génin, J.M.R
Format: Artikel
Sprache:eng
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Zusammenfassung:Oxidation processes of the initial products at any value of the ratio R = {[FeSO 4]/[OH −]} initial is characterized by a reduction in the overall oxidation time as the temperature of the medium increases; this has been valuable in the determination of the various activation energies. Magnetite predominates as the oxidation end product at the characteristic point B, where R = 0.5, at all temperatures; this confirms the proposed mechanism of formation of magnetite from ferrous hydroxide.
ISSN:0010-938X
1879-0496
DOI:10.1016/0010-938X(91)90017-J