A study on the characteristics of CO oxidation at room temperature by metallic Pt
Various experiments and analysis were conducted in order to manufacture a catalyst that could very efficiently oxidize carbon monoxide at room temperature and also to identify the relevant factors influencing the oxidation reaction. Pt/TiO 2 catalyst can increase the oxidizing capability of CO at lo...
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Veröffentlicht in: | Journal of hazardous materials 2010-06, Vol.178 (1), p.917-925 |
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Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | Various experiments and analysis were conducted in order to manufacture a catalyst that could very efficiently oxidize carbon monoxide at room temperature and also to identify the relevant factors influencing the oxidation reaction. Pt/TiO
2 catalyst can increase the oxidizing capability of CO at low temperature and room temperature by reduction. In FT-IR experiments, the catalyst that displayed excellent activity was capable of efficiently oxidizing CO to CO
2 using atmospheric oxygen. Based on the results of XPS analysis, we found that the reduced catalyst changed the platinum's oxidation value to Pt
+2 and Pt
+0. Through the O
2-reoxidation experiments, the catalyst, which consisted of non-stoichiometric platinum oxidized species, displayed an excellent ability to accept oxygen. In this study, the Pt/TiO
2 catalyst was able to very efficiently oxidize CO at low temperature and room temperature even with a minute quantity of platinum. |
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ISSN: | 0304-3894 1873-3336 |
DOI: | 10.1016/j.jhazmat.2010.02.025 |