A study on the characteristics of CO oxidation at room temperature by metallic Pt

Various experiments and analysis were conducted in order to manufacture a catalyst that could very efficiently oxidize carbon monoxide at room temperature and also to identify the relevant factors influencing the oxidation reaction. Pt/TiO 2 catalyst can increase the oxidizing capability of CO at lo...

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Veröffentlicht in:Journal of hazardous materials 2010-06, Vol.178 (1), p.917-925
Hauptverfasser: Seo, Phil Won, Choi, Hyun Jin, Hong, Suk In, Hong, Sung Chang
Format: Artikel
Sprache:eng
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Zusammenfassung:Various experiments and analysis were conducted in order to manufacture a catalyst that could very efficiently oxidize carbon monoxide at room temperature and also to identify the relevant factors influencing the oxidation reaction. Pt/TiO 2 catalyst can increase the oxidizing capability of CO at low temperature and room temperature by reduction. In FT-IR experiments, the catalyst that displayed excellent activity was capable of efficiently oxidizing CO to CO 2 using atmospheric oxygen. Based on the results of XPS analysis, we found that the reduced catalyst changed the platinum's oxidation value to Pt +2 and Pt +0. Through the O 2-reoxidation experiments, the catalyst, which consisted of non-stoichiometric platinum oxidized species, displayed an excellent ability to accept oxygen. In this study, the Pt/TiO 2 catalyst was able to very efficiently oxidize CO at low temperature and room temperature even with a minute quantity of platinum.
ISSN:0304-3894
1873-3336
DOI:10.1016/j.jhazmat.2010.02.025