Polar-Molecule-Dominated Electrorheological Fluids Featuring High Yield Stresses

Recent works on the development of various electrorheological (ER) fluids composed of TiO2, SrTiO, and CaTiO particles coated with CO/HO polar groups are summarized, in which an extremely large yield stress up to 200 kPa is measured and the dynamical yield stress reaches 117 kPa at a shear rate of 775 s−1. Moreover, unlike that of traditional dielectric ER fluids, the yield stress displays a linear dependence on electric field strength. Experimental results reveal that it is the polar molecules adsorbed onto the dielectric particles that play the decisive role: the polar‐molecule‐dominated ER effect arises from the alignment of polar molecules by the enhanced local electric field in the gap between neighboring particles. The pretreatment of electrodes and the contrivance of new measuring procedures, which are desirable for the characterization and practical implementation of this material, are also discussed. The successful synthesis of these fluids has made many of the long since conceived applications of the ER effect available. Polar‐molecule‐dominated electrorheological effects arising from the alignment of polar molecules on particles under electrical field can bring forth shear yield strengths over 200 KPa, thus opening the possibility for the practical implementation of electrorheological fluids. In the current research news the preparation of this new kind of electrorheological fluid, its functioning mechanism, and the pretreatment of electrodes and the contrivance of new measuring procedures for characterization and application, are discussed.