Controlled polymerization of methyl methacrylate in the presence of an FeCl3-complexing agent system

Controlled polymerization of methyl methacrylate in the presence of an FeCl3-complexing agent system

The controlled polymerization of methyl methacrylate in DMF with participation of FeCl 3 and ligands (acrylamide, 1,1,1,3,3,3-hexamethyldisilazane, citric acid, and sulfosalicylic acid) has been studied. It has been shown for the first time that DMF ensures the polymerization of methyl methacrylate...

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Veröffentlicht in:Polymer science. Series B 2009-10, Vol.51 (9-10), p.389-394
Hauptverfasser: Bulgakova, S. A., Tumakova, E. S., Semchikov, Yu. D.
Format: Artikel
Sprache:eng
Schlagworte:
Chemistry
Chemistry and Materials Science
Polymer Sciences
Polymerization
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Zusammenfassung:The controlled polymerization of methyl methacrylate in DMF with participation of FeCl 3 and ligands (acrylamide, 1,1,1,3,3,3-hexamethyldisilazane, citric acid, and sulfosalicylic acid) has been studied. It has been shown for the first time that DMF ensures the polymerization of methyl methacrylate in the controlled mode without any other complexing agents. As temperature increases, the rate of the process and the polydispersity of PMMA increase.
ISSN:1560-0904
1555-6123
DOI:10.1134/S1560090409090103