Biotransformation of zerumbone by Caragana chamlagu

Suspension cultured cells of Caragana chamlagu (Leguminosae) converted zerumbone (1) into zerumbone epoxide (2) as the intermediate, (2R,3R,7R)-2,3-epoxy-9-humulen-8-one (3) and (2R,3S,7R)-2,3-epoxy-9-humulen-8-one (4) as new sesquiterpenes in 11%, 36% and 21% yields, respectively.

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Bibliographische Detailangaben
Veröffentlicht in:	Biotechnology letters 2008-11, Vol.30 (11), p.2025-2029
Hauptverfasser:	Sakamaki, Hiroshi, Itoh, Ken-ichi, Kitanaka, Susumu, Sawada, Seiji, Horiuchi, C. Akira
Format:	Artikel
Sprache:	eng
Schlagworte:	Applied Microbiology Biochemistry Bioconversions. Hemisynthesis Bioengineering Biological and medical sciences Biomedical and Life Sciences Biotechnology Biotransformation Caragana Caragana - cytology Caragana - metabolism Catalysts Cellular biology Fundamental and applied biological sciences. Psychology Life Sciences Mass Spectrometry Methods. Procedures. Technologies Microbiology Molecular Structure Original Research Paper Sesquiterpenes - chemistry Sesquiterpenes - metabolism
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Beschreibung
Zusammenfassung:	Suspension cultured cells of Caragana chamlagu (Leguminosae) converted zerumbone (1) into zerumbone epoxide (2) as the intermediate, (2R,3R,7R)-2,3-epoxy-9-humulen-8-one (3) and (2R,3S,7R)-2,3-epoxy-9-humulen-8-one (4) as new sesquiterpenes in 11%, 36% and 21% yields, respectively.
ISSN:	0141-5492 1573-6776
DOI:	10.1007/s10529-008-9783-5