Synthesis and Characterization of Neutral, Homo and Heteronuclear Clusters with Unsubstituted Germanium or Tin Atoms

Synthesis and Characterization of Neutral, Homo and Heteronuclear Clusters with Unsubstituted Germanium or Tin Atoms

The first, well‐characterized, polyhedral cluster with two different heavier group 14 elements is prepared (see picture). Low‐valent group 14 halides are used to synthesize species in which the majority of the group 14 atoms carry no organic substituents.

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Veröffentlicht in:Angewandte Chemie International Edition 2003-09, Vol.42 (34), p.4071-4074
Hauptverfasser: Richards, Anne F., Hope, Håkon, Power, Philip P.
Format: Artikel
Sprache:eng
Schlagworte:
cluster compounds
germanium
terphenyls
tin
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Zusammenfassung:The first, well‐characterized, polyhedral cluster with two different heavier group 14 elements is prepared (see picture). Low‐valent group 14 halides are used to synthesize species in which the majority of the group 14 atoms carry no organic substituents.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200351907